Barcelona refused to stay indoors this May.
Merchandise spilled outside shops onto the streets, restaurateurs parked diners under trees, and ice-cream cones begged to be eaten on park benches. People thronged the streets, markets filled public squares, and the scents of flowers wafted from vendors’ stalls. I couldn’t blame the city. Its sunshine could have drawn Merlin out of his crystal cave. Insofar as a city lives, Barcelona epitomized a quotation by thermodynamicist Ilya Prigogine: “The main character of any living system is openness.”
Prigogine (1917–2003), who won the Nobel Prize for chemistry, had brought me to Barcelona. I was honored to receive, at the Joint European Thermodynamics Conference (JETC) there, the Ilya Prigogine Prize for a thermodynamics PhD thesis. The JETC convenes and awards the prize biennially; the last conference had taken place in Budapest. Barcelona suited the legacy of a thermodynamicist who illuminated open systems.
Ilya Prigogine began his life in Russia, grew up partially in Germany, settled in Brussels, and worked at American universities. His nobelprize.org biography reveals a mind open to many influences and disciplines: Before entering university, his “interest was more focused on history and archaeology, not to mention music, especially piano.” Yet Prigogine pursued chemistry.
He helped extend thermodynamics outside equilibrium. Thermodynamics is the study of energy, order, and time’s arrow in terms of large-scale properties, such as temperature, pressure, and volume. Many physicists think that thermodynamics describes only equilibrium. Equilibrium is a state of matter in which (1) large-scale properties remain mostly constant and (2) stuff (matter, energy, electric charge, etc.) doesn’t flow in any particular direction much. Apple pies reach equilibrium upon cooling on a countertop. When I’ve described my research as involving nonequilibrium thermodynamics, some colleagues have asked whether I’ve used an oxymoron. But “nonequilibrium thermodynamics” appears in Prigogine’s Nobel Lecture.
Another Nobel laureate, Lars Onsager, helped extend thermodynamics a little outside equilibrium. He imagined poking a system gently, as by putting a pie on a lukewarm stovetop or a magnet in a weak magnetic field. (Experts: Onsager studied the linear-response regime.) You can read about his work in my blog post “Long live Yale’s cemetery.” Systems poked slightly out of equilibrium tend to return to equilibrium: Equilibrium is stable. Systems flung far from equilibrium, as Prigogine showed, can behave differently.
A system can stay far from equilibrium by interacting with other systems. Imagine placing an apple pie atop a blistering stove. Heat will flow from the stove through the pie into the air. The pie will stay out of equilibrium due to interactions with what we call a “hot reservoir” (the stove) and a “cold reservoir” (the air). Systems (like pies) that interact with other systems (like stoves and air), we call “open.”
You and I are open: We inhale air, ingest food and drink, expel waste, and radiate heat. Matter and energy flow through us; we remain far from equilibrium. A bumper sticker in my high-school chemistry classroom encapsulated our status: “Old chemists don’t die. They come to equilibrium.” We remain far from equilibrium—alive—because our environment provides food and absorbs heat. If I’m an apple pie, the yogurt that I ate at breakfast serves as my stovetop, and the living room in which I breakfasted serves as the air above the stove. We live because of our interactions with our environments, because we’re open. Hence Prigogine’s claim, “The main character of any living system is openness.”
JETC 2019 fostered openness. The conference sessions spanned length scales and mass scales, from quantum thermodynamics to biophysics to gravitation. One could arrive as an expert in cell membranes and learn about astrophysics.
I remain grateful for the prize-selection committee’s openness. The topics of earlier winning theses include desalination, colloidal suspensions, and falling liquid films. If you tipped those topics into a tube, swirled them around, and capped the tube with a kaleidoscope glass, you might glimpse my thesis’s topic, quantum steampunk. Also, of the nine foregoing Prigogine Prize winners, only one had earned his PhD in the US. I’m grateful for the JETC’s consideration of something completely different.
When Prigogine said, “openness,” he referred to exchanges of energy and mass. Humans can exhibit openness also to ideas. The JETC honored Prigogine’s legacy in more ways than one. Here’s hoping I live up to their example.