# Generally speaking

My high-school calculus teacher had a mustache like a walrus’s and shoulders like a rower’s. At 8:05 AM, he would demand my class’s questions about our homework. Students would yawn, and someone’s hand would drift into the air.

“I have a general question,” the hand’s owner would begin.

“Only private questions from you,” my teacher would snap. “You’ll be a general someday, but you’re not a colonel, or even a captain, yet.”

Then his eyes would twinkle; his voice would soften; and, after the student asked the question, his answer would epitomize why I’ve chosen a life in which I use calculus more often than laundry detergent.

Many times though I witnessed the “general” trap, I fell into it once. Little wonder: I relish generalization as other people relish hiking or painting or Michelin-worthy relish. When inferring general principles from examples, I abstract away details as though they’re tomato stains. My veneration of generalization led me to quantum information (QI) theory. One abstract theory can model many physical systems: electrons, superconductors, ion traps, etc.

Little wonder that generalizing a QI model swallowed my summer.

QI has shed light on statistical mechanics and thermodynamics, which describe energy, information, and efficiency. Models called resource theories describe small systems’ energies, information, and efficiencies. Resource theories help us calculate a quantum system’s value—what you can and can’t create from a quantum system—if you can manipulate systems in only certain ways.

Suppose you can perform only operations that preserve energy. According to the Second Law of Thermodynamics, systems evolve toward equilibrium. Equilibrium amounts roughly to stasis: Averages of properties like energy remain constant.

Out-of-equilibrium systems have value because you can suck energy from them to power laundry machines. How much energy can you draw, on average, from a system in a constant-temperature environment? Technically: How much “work” can you draw? We denote this average work by < W >. According to thermodynamics, < W > equals the change ∆F in the system’s Helmholtz free energy. The Helmholtz free energy is a thermodynamic property similar to the energy stored in a coiled spring.

One reason to study thermodynamics?

Suppose you want to calculate more than the average extractable work. How much work will you probably extract during some particular trial? Though statistical physics offers no answer, resource theories do. One answer derived from resource theories resembles ∆F mathematically but involves one-shot information theory, which I’ve discussed elsewhere.

If you average this one-shot extractable work, you recover < W > = ∆F. “Helmholtz” resource theories recapitulate statistical-physics results while offering new insights about single trials.

Helmholtz resource theories sit atop a silver-tasseled pillow in my heart. Why not, I thought, spread the joy to the rest of statistical physics? Why not generalize thermodynamic resource theories?

The average work <W > extractable equals ∆F if heat can leak into your system. If heat and particles can leak, <W > equals the change in your system’s grand potential. The grand potential, like the Helmholtz free energy, is a free energy that resembles the energy in a coiled spring. The grand potential characterizes Bose-Einstein condensates, low-energy quantum systems that may have applications to metrology and quantum computation. If your system responds to a magnetic field, or has mass and occupies a gravitational field, or has other properties, <W > equals the change in another free energy.

A collaborator and I designed resource theories that describe heat-and-particle exchanges. In our paper “Beyond heat baths: Generalized resource theories for small-scale thermodynamics,” we propose that different thermodynamic resource theories correspond to different interactions, environments, and free energies. I detailed the proposal in “Beyond heat baths II: Framework for generalized thermodynamic resource theories.”

“II” generalizes enough to satisfy my craving for patterns and universals. “II” generalizes enough to merit a hand-slap of a pun from my calculus teacher. We can test abstract theories only by applying them to specific systems. If thermodynamic resource theories describe situations as diverse as heat-and-particle exchanges, magnetic fields, and polymers, some specific system should shed light on resource theories’ accuracy.

If you find such a system, let me know. Much as generalization pleases aesthetically, the detergent is in the details.

# Apply to join IQIM!

Editor’s Note: Dr. Chandni Usha is an IQIM postdoctoral scholar working with Prof. Eisenstein. We asked her to describe her experience as an IQIM fellow.

Just another day at work!

When I look back at how I ended up here, I find myself in a couple of metastable states. Every state pushed me to newer avenues of knowledge. Interestingly, growing up I never really knew what it was like to be a scientist. I had not watched any of those sci-fi movies or related TV series as a kid. No outreach program ever reached me in my years of schooling! My first career choice was to be a lawyer. But a casual comment by a friend that lawyers are ‘liars’ was strong enough to change my mind. Strangely enough, now the quest is for the truth, in a lab down at the sub-basement of one of the world’s best research institutes.

I did my masters in Physics at this beautiful place called the Indian Institute of Science in Bangalore. I realized that I like doing things with my hands. Fixing broken instruments seemed fun. Every new data point on a plot amused me. It was more than obvious that experimental physics is where my heart was and hence I went on to do a Ph.D. in condensed matter physics. When I decided to apply for postdoctoral positions, an old friend of mine, Debaleena Nandi, told me to look up the IQIM website. That was in November 2012, and I applied for the IQIM postdoctoral fellowship. My stars were probably aligned to be here. Coincidentally, Jim Eisenstein, my adviser, was in India on a sabbatical and I happened to hear him give a talk. It left such a strong impression in my mind that I was willing to give up on a trip to Europe for an interview the next day had he offered me a position. We spoke about possible problems, but no offer was in sight and hence I did travel to Europe with my mind already at Caltech. IQIM saved me from my dilemma when they offered me the fellowship a few days later.

Now, why choose IQIM! Reason number one was Jim. And reason number two was this blog which brought in this feeling that there exists a community here; where experimentalists and theorists could share their ideas and grow together in a symbiotic manner. My first project was with an earlier postdoc, Erik Henriksen, who is now a faculty at Washington University in St. Louis. It was based on a proposal by fellow IQIM professor Jason Alicea which involved decorating a film of graphene with a certain heavy metal adatom. Jason’s prediction was that if you choose the right adatom, it could endow some of its unique properties such as strong spin-orbit coupling to the underlying graphene sheet. One can thus engineer graphene to what is called a topological insulator where only the edges of the graphene sheet conduct. Erik had taken on this task and I tagged along. Working in a very small campus with a close-knit community helps bounce your ideas around others and that’s how this experiment came into being. I found it particularly interesting that Jason and his colleagues often ask us, the experimentalists, whether some of the ideas they have are actually feasible to be performed in a lab!

The IQIM fellowship allows you to work on a variety of fields that come under the common theme of quantum information and matter. In addition to providing an independent funding and research grant, the fellowship offers the flexibility to work with any mentor and even multiple mentors, especially in the theory group. In experimental groups however, that flexibility is limited but not impossible. The fellowship gives you a lot of freedom and encourages collaborations. IQIM theory folks have a very strong and friendly group with a lot of collaborations, to the extent that it is often hard to distinguish the faculty from the postdocs and students.

Apart from a yearly retreat to a beautiful resort in Lake Arrowhead, the social life at IQIM is further enhanced through the Friday seminars where you get to hear about the work from postdocs and graduate students from IQIM, as well as other universities. IQIM’s outreach activities have been outstanding. A quick look at this blog will take you from the PhD Comics animations, to teaching kids quantum mechanics through Miinecraft, to hosting middle school students at the InnoWorks academy and a host of other activities. This note will not be complete without mentioning about our repeated efforts to attract women candidates. My husband lives in India, and I live right across the globe, all for the love of science. I am not alone in this respect as we have two more women postdocs at IQIM who have similar stories to tell. So, if you are a woman and wish to pursue a quality research program, this is the place to be, for together we can bring change.

Now that I have convinced you that IQIM is something not to be missed, kindly spread the word. And if you are looking for an awesome opportunity to work at Caltech, get your CV and research statement and apply for the fellowships before Dec 5, 2014!

# Science at Burning Man: Say What?

Burning Man… what a controversial topic these days. The annual festival received quite a bit of media attention this year, with a particular emphasis on how the ‘tech elite’ do burning man. Now that we are no longer in the early September Black Rock City news deluge I wanted to forever out myself as a raging hippie and describe why I keep going back to the festival: for the science of course!

This is a view of my camp, the Phage, as viewed from the main street in Black Rock City. I have no idea why the CH-47 is doing a flyover… everything else is completely standard for Burning Man. Notice the 3 million Volt Tesla coil which my roommates built.

I suspect that at this point, this motivation may seem counter-intuitive or even implausible, but let me elaborate. First, we should start with a question: what is Burning Man? Answer: this question is impossible to answer. The difficulty of answering this question is why I’m writing this post. Most people oversimplify and describe the event as a ‘bunch of hippies doing drugs in the desert’ or as ‘a music festival with a dash of art’ or as ‘my favorite time of the year’ and on and on. There are nuggets of truth in all of these answers but none of them convey the diversity of the event. With upwards of 65,000 people gathered for a week, my friends and I like to describe it as a “choose your own adventure” sort of experience. I choose science.

My goal for this post is to give you a sense of the sciency activities which take place in my camp. Coupling this with the fact that science is a tiny subset of the Burning Man ethos, you should come away convinced that there’s much more to the festival than just ‘a bunch of hippies doing drugs in the desert and listening to music.’

I camp with The Phage, as in bacteriophage, the incredibly abundant virus which afflicts bacteria. There are about 200 people in our camp, most of whom are scientists, with a median age of over 30. Only about 100 people camp with the Phage in any given year. The camp also houses some hackers, entrepreneurs and artists but scientific passion is unequivocally our unifying trait. Some of the things we assembled this year include:

Dr. F and Dr. B’s 3 million Volt musical Tesla coil. Humans were inserted for scale.

Musical Tesla coil: two of my roommates built a 3 million Volt musical Tesla coil. Think about this… it’s insane. The project started while they were writing their Caltech PhD theses (EE and Applied Physics) and in my opinion, the Tesla coil’s scale is a testament to the power of procrastination! Thankfully, they both finished their PhDs. After doing so, they spent the months between their defenses and Burning Man building the coil in earnest. Not only was the coil massive–with the entire structure standing well over 20 feet tall–but it was connected through MIDI to a keyboard. Sound is just pressure waves moving through air, and lightning moves lots of air, so this was one of the loudest platforms on the playa. I manned the coil one evening and one professional musician told me it was “by far the coolest instrument he has ever played.” Take a brief break from reading this and watch this video!

Dr. Brainlove getting ready for a midnight stroll and then getting a brainlift.

Dr. Brainlove: we built a colossal climbable “art car” in the shape of a brain which was covered in LEDs and controlled from a wireless EEG device. Our previous art car (Dr. Strangelove) died at the 2013 festival, so last winter our community rallied and ‘brainstormed’ the theme for this vehicle. After settling on a neuroscience theme, one of my campmates in Berkeley scanned her brain and sent a CAD file to Arcology Now in Austin, TX who created an anatomically correct steel frame. We procured a yellow school bus which had been converted to bio diesel. We raised over \$30k (there were donations beyond indiegogo.) About 20 of my campmates volunteered their weekends to work at the Nimby in Oakland: hacking apart the bus, building additional structures, covering the bus with LEDs, installing a sound system, etc. One of the finishing touches was that one of my campmates who is a neurosurgeon at UCSD procured some wireless EEG devices and then he and some friends wrote software to control Dr. Brainlove’s LEDs–thus displaying someone’s live brain activity on a 30′ long by 20′ tall climbable musical art car for the entire playa to see! We already have plans to increase the LED density and therefore put on a more impressive interactive neural light show next year.

Sugarcubes: in 2013, some campmates built an epic LED sculpture dubbed “the sugarcubes”. Just watch this video and you’ll be blown away. The cubes weren’t close to operational when they arrived so there was 48 hours of hacking madness by Dan Kaminsky, Alexander Green and many brilliant others before our “Tuesday night” party. The ethos is similar to the Caltech undergrad’s party culture–the fun is in the building–don’t tell my friends but I slept through the actual party.

Ask a scientist on the left (I’m in there somewhere and so is one of my current roommates– another Caltech PhD ’13.) Science class on the right. Science everywhere!

Ask a scientist: there’s no question that this is my favorite on playa activity. This photo doesn’t do the act justice. Imagine a rotating cast of 7-8 phagelings braving dust storms and donning lab coats all FOR SCIENCE! The diversity of questions is incredible and I always learn a tremendous amount (evidenced by losing my voice three years running.) For example, this year, a senior executive at Autodesk approached and asked me a trick question related to the Sun’s magnetic field. Fear not–I was prepared! This has happened before.. and he was wearing a “space” t-shirt so my guard was up. A nuclear physicist from UCLA asked me to explain Bell test experiments (and he didn’t even know my background.) Someone asked how swamp coolers work? To be honest, I didn’t have a clear answer off the top of my head so I called over one of my friends (who was one of the earliest pioneers of optogenetics) and he nailed it immediately. Not having a clear answer to this question was particularly embarrassing because I’ve spent most of the past year thinking about something akin to quantum thermodynamics… if you can call black hole physics and holographic entanglement that.

Make/hack sessions: I didn’t participate in any of these this year but some of my campmates teach soldering/microscopy/LED programming/etc classes straight out of our camp. See photo above.

EEG and LED hacking.

Science talks: we had 4-5 science talks in a carpeted 40ft geodesic dome every evening. This is pretty self explanatory and by this point in my post, the Phage may have enough credibility that you’d believe the caliber is exceptional.

Impromptu conversations: this is another indescribable aspect. I’ll risk undermining the beauty of these conversations by using a cheap word: the ‘networking’ at Burning Man is unrivaled. I don’t mean in the for-dollar-profit sense, I mean in the intellectual and social sense. For example, one of my campmates’ brother is a string theory postdoc at Stanford. He came by our camp one evening, we were introduced, and then we met up again in the default world when I visited Stanford the following week. Burning Man is the type of place where you’ll start talking about MPEG/EFF/optogenetics/companyX/etc and then someone will say: “you know that the inventor/spokesperson/pioneer/founder/etc is at the next table over right?”

Yup, Burning Man is just a bunch of hippies doing drugs in the desert. You shouldn’t come. You definitely wouldn’t enjoy it. No fun is had and no ideas are shared. Or in other words, Burning Man: where exceptionally capable people prepare themselves for the zombie apocalypse.

Check out my friend Peretz Partensky’s Flickr feed if you want to see more photos (and credit goes to him for the photos in this post.)

# Making sci-fi teleportation sound less crazy

Laser beam bending due to a change in the speed of light in water.

If you ever wanted to see a sci-fi plot that expertly applied advanced physical concepts so that with a bit of imagination teleporting a human was not as unbelievable as most of the teleportation scenarios we see in the movies, keep reading.

Years ago, when I was still in Russia, I was working on a back-story for a sci-fi game I was playing with friends. In the game, players were given stones (from Mars!) that could change the fundamental constants of nature: electron charge e, speed of light c and Planck constant h. I had already worked out the effects these stones would produce on the space around them (I suggest it as an exercise to the nerdy reader – once you are done thinking about it, see my answer below), so my next task was to envision a big scientific project centered around those stones, with a solid foundation on real physics and a portal to Mars as a final goal. As it turned out, some unforeseen consequences included blowing up the whole lab and scattering the stones in the nearby forest. That’s the back-story.

It all worked beautifully on paper. I imagined that materials could be programmed to obey different values of fundamental constants. These Martian stones were supposed to be the first encounter humanity had with matter where such effects could be observed and studied. The effects extended to a region around the stone, with weird things happening on the boundary of that region. For one thing, energy was not conserved in the vicinity of these stones.

Now having control over e, c and h, the scientists would leverage this new-found power to try to move the fine structure constant $e^2/(\hbar c)$ to what is known as the Landau pole. Such a feat would result in infinitely strong interactions between particles, so that the energetic content of space-time would jump through the roof and a black hole would form. If one was lucky, even a traversable wormhole would form, which is what the scientists were hoping for, because back on Mars these things could have formed naturally, and the lab wormhole would connect to the Martian network.

If you’ve read all this and are asking yourself “What just happened?”, see all the physical concepts explained below: Continue reading

# The experimentalist next door

At 9:10 AM, the lab next door was blasting “Born to Be Wild.”

I was at Oxford, moonlighting as a visiting researcher during fall 2013. My hosts included quantum theorists in Townsend Laboratory, a craggy great-uncle of a building. Poke your head out of the theory office, and Experiment would flood your vision. Our neighbors included laser wielders, ion trappers, atom freezers, and yellow signs that warned, “DANGER OF DEATH.”

Down the corridor in Townsend Laboratory.

Hardly the neighborhood Mr. Rogers had in mind.

The lab that shared a wall with our office blasted music. To clear my head of calculations and of Steppenwolf, I would roam the halls. Some of the halls, that is. Other halls had hazmat warnings instead of welcome mats. I ran into “RADIATION,” “FIRE HAZARD,” “STRONG MAGNETIC FIELDS,” “HIGH VOLTAGE,” and “KEEP THIS TOILET NEAT AND TIDY.” Repelled from half a dozen doors, I would retreat to the office. Kelly Clarkson would be cooing through the wall.

“We can hear them,” a theorist observed about the experimentalists, “but they can’t hear us.”

Dangers lurked even in the bathroom.

Experiment should test, disprove, and motivate theories; and theory should galvanize and (according to some thinkers) explain experiments. But some theorists stray from experiment like North America from Pangaea.

The theoretical physics I’ve enjoyed is abstract. I rarely address platforms, particular physical systems in which theory might incarnate. Quantum-information platforms include electrons in magnetic fields, photons (particles of light), ion trapsquantum dots, and nuclei such as the ones that image internal organs in MRI machines.

Instead of addressing electrons and photons, I address mathematics and abstract physical concepts. Each of these concepts can incarnate in different forms in different platforms. Examples of such concepts include preparation procedures, evolutions, measurements, and memories. One preparation procedure defined by one piece of math can result from a constant magnetic field in one platform and from a laser in another. Abstractness has power, enabling one idea to describe diverse systems.

I’ve enjoyed wandering the hills and sampling the vistas of Theory Land. Yet the experimentalist next door cranked up the radio of reality in my mind. “We can hear them,” a theorist said. In Townsend Laboratory, I began listening. My Oxford collaborators and I interwove two theoretical frameworks that describe heat transferred and work performed on small scales. One framework, one-shot statistical mechanics, has guest-starred on this blog.

The other framework consists of fluctuation relations, which describe deviations from average behaviors by small physical systems. A quantum particle on one side of a wall has a tiny probability of tunneling through without boring any hole. Since the probability is tiny, the average particle doesn’t tunnel (during any reasonably short amount of time). When analyzing macroscopic systems—say, the roughly 1024 atoms that form your left thumbnail—we assume that every particle behaves like the average particle. We can’t when analyzing minuscule systems such as one short strand of DNA. Deviations from average behaviors appear in experimental data about small systems as they do not appear in data about large systems. Fluctuation relations help us understand those deviations.

My colleagues and I addressed “information,” “systems,” and “interactions.” We deployed abstract ideas, referencing platforms only when motivating our work. Then a collaborator challenged me to listen through the wall.

Experimentalists have tested fluctuation relations. Why not check whether their data supports our theory? At my friend’s urging, I contacted experimentalists who’d shown that DNA obeys a fluctuation relation. The experimentalists had unzipped and re-zipped single DNA molecules using optical tweezers, which resemble ordinary tweezers but involve lasers. Whenever the experimentalists pulled the DNA, they measured the force they applied. They concluded that their platform obeyed an abstract fluctuation theorem. The experimentalists generously shared their data, which supported our results.

Experimentalists unzipped and rezipped DNA to test fluctuation relations. This depiction of the set-up comes from this article.

My colleagues and I didn’t propose experiments. We didn’t explain why platforms had behaved in unexpected ways. We checked calculations with recycled data. But we ventured outside Theory Land. We learned that one-shot theory models systems modeled also by fluctuation relations, which govern experiments. This link from one-shot theory to experiment, like the forbidden corridors in Townsend Laboratory, invite exploration.

In Townsend, I didn’t suffer the electric shocks or the explosions advertised on the doors (though the hot water in the bathroom nearly burned me). I turned out not to need those shocks. Blasting rock music at 9:10 AM can wake even a theorist up to reality.

# Where are you, Dr. Frank Baxter?

This year marks the 50th anniversary of my first publication. In 1964, when we were eleven-year-old fifth graders, my best friend Mace Rosenstein and I launched The Pres-stein Gazette, a not-for-profit monthly. Though the first issue sold well, the second issue never appeared.

Front page of the inaugural issue of the Pres-stein Gazette. Faded but still legible, it was produced using a mimeograph machine, a low-cost printing press which was popular in the pre-Xerox era.

One of my contributions to the inaugural  issue was a feature article on solar energy, which concluded that fossil fuel “isn’t of such terrific abundance and it cannot support the world for very long. We must come up with some other source of energy. Solar energy is that source …  when developed solar energy will be a cheap powerful “fuel” serving the entire world generously forever.”

This statement holds up reasonably well 50 years later. You might wonder how an eleven-year-old in 1964 would know something like that. I can explain …

In the 1950s and early 1960s, AT&T and the Bell Telephone System produced nine films about science, which were broadcast on prime-time network television and attracted a substantial audience. After broadcast, the films were distributed to schools as 16 mm prints and frequently shown to students for many years afterward. I don’t remember seeing any of the films on TV, but I eventually saw all nine in school. It was always a treat to watch one of the “Bell Telephone Movies” instead of hearing another boring lecture.

For educational films, the production values were uncommonly high. Remarkably, the first four were all written and directed by the legendary Frank Capra (a Caltech alum), in consultation with a scientific advisory board provided by Bell Labs.  Those four (Our Mr. Sun, Hemo the Magnificent, The Strange Case of the Cosmic Rays, and Unchained Goddess, originally broadcast in 1956-58) are the ones I remember most vividly. DVDs of these films exist, but I have not watched any of them since I was a kid.

The star of the first eight films was Dr. Frank Baxter, who played Dr. Research, the science expert. Baxter was actually an English professor at USC who had previous television experience as the popular host of a show about Shakespeare, but he made a convincing and pleasingly avuncular scientist. (The ninth film, Restless Sea, was produced by Disney, and Walt Disney himself served as host.) The other lead role was Mr. Writer, a skeptical and likeable Everyman who learned from Dr. Research’s clear explanations and sometimes translated them into vernacular.

The first film, Our Mr. Sun, debuted in 1956 (broadcast in color, a rarity at that time) and was seen by 24 million prime-time viewers. Mr. Writer was Eddie Albert, a well-known screen actor who later achieved greater fame as the lead on the 1960s TV situation comedy Green Acres. Lionel Barrymore appeared in a supporting role.

Dr. Frank Baxter and Eddie Albert in Our Mr. Sun. (Source: Wikipedia)

Our Mr. Sun must have been the primary (unacknowledged) source for my article in the Pres-stein Gazette.  Though I learned from Wikipedia that Capra insisted (to the chagrin of some of his scientific advisers) on injecting some religious themes into the film, I don’t remember that aspect at all. The scientific content was remarkably sophisticated for a film that could be readily enjoyed by elementary school students, and I remember (or think I do) clever animations teaching me about the carbon cycle in stellar nuclear furnaces and photosynthesis as the ultimate source of all food sustaining life on earth. But I was especially struck by Dr. Baxter’s dire warning that, as the earth’s population grows, our planet will face shortages of food and fuel. On a more upbeat note he suggested that advanced technologies for harnessing the power of the sun would be the key to our survival, which inspired the optimistic conclusion of my article.

A lavishly produced prime-time show about science was a real novelty in 1956, many years before NOVA or the Discovery Channel. I wonder how many readers remember seeing the Dr. Frank Baxter movies when you were kids, either on TV or in school. Or was there another show that inspired you like Our Mr. Sun inspired me? I hope some of you will describe your experiences in the comments.

And I also wonder what resource could have a comparable impact on an eleven-year-old in today’s very different media environment. The obvious comparison is with Neil deGrasse Tyson’s revival of Cosmos, which aired on Fox in 2014. The premiere episode of Cosmos drew 8.5 million viewers on the night it was broadcast, but that is a poor measure of impact nowadays. Each episode has been rebroadcast many times, not just in the US and Canada but internationally as well, and the whole series is now available in DVD and Blu-ray. Will lots of kids in the coming years own it and watch it? Is Cosmos likely to be shown in classrooms as well?

Science is accessible to the curious through many other avenues today, particularly on YouTube. One can watch TED talks, or Minute Physics, or Veritasium, or Khan Academy, or Lenny Susskind’s lectures, not to mention our own IQIM videos on PHD Comics. And there are many other options. Maybe too many?

But do kids watch this stuff? If not, what online sources inspire them? Do they get as excited as I did when I watched Dr. Frank Baxter at age 11?

I don’t know. What do you think?

# The Graphene Effect

Lunch with Spiros, Eryn, and Jackie at the Athenaeum (left to right).

Sitting and eating lunch in the room where Einstein and many others of turbo charged, ultra-powered acumen sat and ate lunch excites me. So, I was thrilled when lunch was arranged for the teachers participating in IQIM’s Summer Research Internship at the famed Athenaeum on Caltech’s campus. Spyridon Michalakis (Spiros), Jackie O’Sullivan, Eryn Walsh and I were having lunch when I asked Spiros about one of the renowned “Millennium” problems in Mathematical Physics I heard he had solved. He told me about his 18 month epic journey (surely an extremely condensed version) to solve a problem pertaining to the Quantum Hall effect. Understandably, within this journey lied many trials and tribulations ranging from feelings of self loathing and pessimistic resignation to dealing with tragic disappointment that comes from the realization that a victory celebration was much ado about nothing because the solution wasn’t correct. An unveiling of your true humanity and the lengths one can push themselves to find a solution. Three points struck me from this conversation. First, there’s a necessity for a love of the pain that tends to accompany a dogged determinism for a solution. Secondly, the idea that a person’s humanity is exposed, at least to some degree, when accepting a challenge of this caliber and then refusing to accept failure with an almost supernatural steadfastness towards a solution. Lastly, the Quantum Hall effect. The first two on the list are ideas I often ponder as a teacher and student, and probably lends itself to more of a philosophical discussion, which I do find very interesting, however, will not be the focus of this posting.

The Yeh research group, which I gratefully have been allowed to join the last three summers, researches (among other things) different applications of graphene encompassing the growth of graphene, high efficiency graphene solar cells, graphene component fabrication and strain engineering of graphene where, coincidentally for the latter, the quantum Hall effect takes center stage. The quantum Hall effect now had my attention and I felt it necessary to learn something, anything, about this recently recurring topic. The quantum Hall effect is something I had put very little thought into and if you are like I was, you’ve heard about it, but surely couldn’t explain even the basics to someone. I now know something on the subject and, hopefully, after reading this post you too will know something about the very basics of both the classical and the quantum Hall effect, and maybe experience a spark of interest regarding graphene’s fascinating ability to display the quantum Hall effect in a magnetic field-free environment.

Let’s start at the beginning with the Hall effect. Edwin Herbert Hall discovered the appropriately named effect in 1879. The Hall element in the diagram is a flat piece of conducting metal with a longitudinal current running through. When a magnetic field is introduced normal to the Hall element the charge carriers moving through the Hall element experience a Lorentz force. If we think of the current as being conventional (direction flow of positively charged ions), then the electrons (negative charge carriers) are traveling in the opposite direction of the green arrow shown in the diagram. Referring to the diagram and using the right hand rule you can conclude a buildup of electrons at the long bottom edge of the Hall element running parallel to the longitudinal current, and an opposing positively charged edge at the long top edge of the Hall element. This separation of charge will produce a transverse potential difference and is labeled on the diagram as Hall voltage (VH). Once the electric force (acting towards the positively charged edge perpendicular to both current and magnetic field) from the charge build up balances with the Lorentz force (opposing the electric force), the result is a negative charge carrier with a straight line trajectory in the opposite direction of the green arrow. Essentially, Hall conductance is the longitudinal current divided by the Hall voltage.

Now, let’s take a look at the quantum Hall effect. On February 5th, 1980 Klaus von Klitzing was investigating the Hall effect, in particular, the Hall conductance of a two-dimensional electron gas plane (2DEG) at very low temperatures around 4 Kelvin (- 4520 Fahrenheit). von Klitzing found when a magnetic field is applied normal to the 2DEG, and Hall conductance is graphed as a function of magnetic field strength, a staircase looking graph emerges. The discovery that earned von Klitzing’s Nobel Prize in 1985 was as unexpected as it is intriguing. For each step in the staircase the value of the function was an integer multiple of e2/h, where e is the elementary charge and h is Planck’s constant. Since conductance is the reciprocal of resistance we can view this data as h/ie2. When i (integer that describes each plateau) equals one, h/ie2 is approximately 26,000 ohms and serves as a superior standard of electrical resistance used worldwide to maintain and compare the unit of resistance.

Before discussing where graphene and the quantum Hall effect cross paths, let’s examine some extraordinary characteristics of graphene. Graphene is truly an amazing material for many reasons. We’ll look at size and scale things up a bit for fun. Graphene is one carbon atom thick, that’s 0.345 nanometers (0.000000000345 meters). Envision a one square centimeter sized graphene sheet, which is now regularly grown. Imagine, somehow, we could thicken the monolayer graphene sheet equal to that of a piece of printer paper (0.1 mm) while appropriately scaling up the area coverage. The graphene sheet that originally covered only one square centimeter would now cover an area of about 2900 meters by 2900 meters or roughly 1.8 miles by 1.8 miles. A paper thin sheet covering about 4 square miles. The Royal Swedish Academy of Sciences at nobelprize.org has an interesting way of scaling the tiny up to every day experience. They want you to picture a one square meter hammock made of graphene suspending a 4 kg cat, which represents the maximum weight such a sheet of graphene could support. The hammock would be nearly invisible, would weigh as much as one of the cat’s whiskers, and incredibly, would possess the strength to keep the cat suspended. If it were possible to make the exact hammock out of steel, its maximum load would be less than 1/100 the weight of the cat. Graphene is more than 100 times stronger than the strongest steel!

Graphene sheets possess many fascinating characteristics certainly not limited to mere size and strength. Experiments are being conducted at Caltech to study the electrical properties of graphene when draped over a field of gold nanoparticles; a discipline appropriately termed “strain engineering.” The peaks and valleys that form create strain in the graphene sheet, changing its electrical properties. The greater the curvature of the graphene over the peaks, the greater the strain. The electrons in graphene in regions experiencing strain behave as if they are in a magnetic field despite the fact that they are not. The electrons in regions experiencing the greatest strain behave as they would in extremely strong magnetic fields exceeding 300 tesla. For some perspective, the largest magnetic field ever created has been near 100 tesla and it only lasted for a few milliseconds. Additionally, graphene sheets under strain experience conductance plateaus very similar to those observed in the quantum Hall effect. This allows for great control of electrical properties by simply deforming the graphene sheet, effectively changing the amount of strain. The pseudo-magnetic field generated at room temperature by mere deformation of graphene is an extremely promising and exotic property that is bound to make graphene a key component in a plethora of future technologies.

Graphene and its incredibly fascinating properties make it very difficult to think of an area of technology where it won’t have a huge impact once incorporated. Caltech is at the forefront in research and development for graphene component fabrication, as well as the many aspects involved in the growth of high quality graphene. This summer I was involved in the latter and contributed a bit in setting up an experiment that will attempt to grow graphene in a unique way. My contribution included the set-up of the stepper motor (pictured to the right) and its controls, so that it would very slowly travel down the tube in an attempt to grow a long strip of graphene. If Caltech scientist David Boyd and graduate student Chen-Chih Hsu are able to grow the long strips of graphene, this will mark yet another landmark achievement for them and Caltech in graphene research, bringing all of us closer to technologies such as flexible electronics, synthetic nerve cells, 500-mile range Tesla cars and batteries that allow us to stream Netflix on smartphones for weeks on end.